One of the things that I love/hate/enjoy/despise about my '66 is that everything is a problem solving endeavor. This is one of those!! I looked at my set up, which is all stock. Stock 289, stock water pump, stock '65 style p/s pump, stock pulleys, etc. Looks like yours. Here's a photo. The p/s pulley looks like it might be closer in than yours. But how it all lines up in a photo is based on the exact angle of the camera so rather than saying for sure, here are some measurements of my set up and maybe by comparing to yours, it may help.
1. p/s pump width from front face to back face: 4-5/32"
2. front edge of p/s mounting bracket to back lip of p/s pulley:
3. pump stub length: 1-9/16
4. front face of p/s pump to back lip of p/s pulley: 1-9/16 (so looking straight down the back side of the pulley, it lines up exactly with the front of the snub) 5/8
5. gap from inside of p/s pulley to end of stub: 1/8
6. I also held a straight edge to the front lip of the pump mounting bracket, where it bolts to the top bolt of the pump, and the straight edge lines up with the back edge of the water pump pulley
Hope that helps!
Bill