Supposedly they changed the firing order on the W to revise main bearing loads but I've never seen any marked difference in durability in any of the performance engines I've been involved with. With either order, the engines spin easily into the 7K+ range with no service or maintenance issues.
As the others mentioned, the cam is ground differently, for the 302 firing order. Performance-wise, if the cam is a good grind for your application, IMO it will make no difference than if the same grind had the W firing order.
The only possible difference I can think of is that you might get a slightly different natural harmonic from an OEM balance engine. Can't prove that one though *G*